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We need to persuade governments to introduce policies that will reduce fossil fuel use, push for increased energy efficiency and so reduce demand for energy, and to increase the uptake of renewable energy and other non-carbon-based technologies. We also need to persuade companies, in particular those whose products use fossil fuels, to make investments that lead to less carbon. And we also need to persuade individuals to switch from unsustainable energy use to more sustainable options.
A meeting of the world’s scientists this week in Incheon, South Korea, will decide what action should be taken. For the first time in a few years, I hope the meetings will give a serious assessment of the opportunities and risks as well as the possible ways of addressing climate change. We are at a fork in the road: we have two equally viable paths. Our decisions about how to choose between them will determine whether we succeed in limiting the temperature rise to 2°C, or whether it will rise to 4°C or more.
It is extremely regrettable that when I was chairing the Intergovernmental Panel on Climate Change (IPCC) panel on mitigation, the world’s leading climate scientists failed to give us a roadmap with the ambition needed to keep the temperature rise from 4°C above pre-industrial levels. As a result of this, governments have not met their obligations to reduce emissions of greenhouse gases, and we have been unable to take action to curb the temperature rise. The panel failed because the world’s leading scientists cannot agree on whether we should aim for a 2°C temperature rise or 4°C increase.
We are now about to find out whether the world’s top scientists will
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The phenomenon of intramolecular isomerization of amino acids to yield a peptide isomer accompanied by significant changes in structural and conformational properties has been studied with a peptide variant of triosephosphate isomerase (TIM) containing the chromogenic peptide sequence H-His-Pro-Ala-Pro-Pro-Trp-OMe-OH (HPAAPW). The peptide has been obtained in two different enantiomeric states: (R)-HPAAPW isomer (R-HPAAPW) and (S)-HPAAPW isomer (S-HPAAPW) by the use of a covalently bound chiral support in the Strecker synthesis. Due to a higher population of the isomeric form, higher yields of the isomer with the (R)-configuration have been observed, leading to the question of an apparent enantioselectivity of the isomerization. Upon collision-induced dissociation (CID), the intact R-HPAAPW and S-HPAAPW isomers undergo significant changes in their conformational structures leading to the appearance of new (minor) mass spectrometric signals for fragment ions (but not for cross-ring cleavage ions) that correspond to loss of a trinitrophenol (TNP) moiety (PNP ion, m/z 413, [M-TNP]+, for R-HPAAPW; and PNP ion, m/z 411, [M-TNP]+, for S-HPAAPW). This results in a dramatic increase in the amount of TNP-related ion (m/z 413) relative to the parent ion of each isomer. Therefore, the new ions arising from loss of the TNP moiety can be considered as good markers for detection of the isomerization process in low enantiomeric excess ratios by CID. The combination of electrospr
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